Coal Conversions Facts 2013


Compiled By Mr. Eric A. McKenzie. PhD. BA. DSM
Coal Convertions FACT 2013



FACT SHEET 01
Basis of Analysis
Definitions
As Received (ar)               : includes Total Moisture (TM)
Air Dried (ad)                    : includes Inherent Moisture (IM) only
Dry Basis (db)                    : excludes all Moisture
Dry Ash Free (daf)           : excludes all Moisture & Ash

The Proximate Analysis of any coal i.e. the % content of Moisture, Ash (A). Volatile Matter (VM), Fixed Carbon (FC) – also Sulphur (S) and Calorific Value (CV) – can be expressed on any of the above bases.
Convertions

To obtain:-
Air Dry
Dry Basis
As Received
 multiply







ar by:
100 - IM%
100

100 - TM%
100 - TM%




ad by:
100
100 - TM%

100 - TM%
100 - IM%




db by:
100 - IM%
100 - TM%

100
100




[For daf, multiply db by 100/(100-A)]



Example:





ar
ad
db
daf
TM
11.0
-
-
-
IM
2.0
2.0
-
-
Ash
12.0
13.2
13.5
-
VM
30.0
33.0
33.7
39.0
FC
47.0
51.8
52.8
61.0
Sulphur
1.0
1.1
1.12
-


FACT SHEET 02
Mass
Units:
Metric ton (t) = tonne = 1000 kilograms (= 2204.6 lb)
Imperial or long ton (lt) = 1016.05 kilograms (= 2240 lb)
Short (US) ton (st) = 907.19 kilograms (= 2000 lb)
Conversions:
From long ton to metric ton multiply by 1.016
From short ton to metric ton multiply by 0.9072

Mt million tonnes
Mtce million tonnes of coal equivalent (= 0.697 Mtoe)
Mtoe million tonnes of oil equivalent

Calorific Values (CV)
 Units:
                kcal/kg – kilocalories per kilogram
MJ/kg* – Megajoules per kilogram
Btu/lb – British thermal units per pound
* 1 MJ/kg = 1 Gigajoule/tonne (GJ/t)

Gross & Net Calorific Values
Gross CV or ‘higher heating value’ (HHV) is the CV under laboratory conditions.
Net CV or ‘lower heating value’ (LHV) is the useful calorific value in boiler plant.
The difference is essentially the latent heat of the water vapour produced.

Conversions – Units
From kcal/kg to MJ/kg multiply kcal/kg by 0.004187
From kcal/kg to Btu/lb multiply kcal/kg by 1.8
From MJ/kg to kcal/kg multiply MJ/kg by 238.8
From MJ/kg to Btu/lb multiply MJ/kg by 429.9
From Btu/lb to kcal/kg multiply Btu/lb by 0.5556
From Btu/lb to MJ/kg multiply Btu/lb by 0.002326

Conversions – Gross/Net (per ISO, for As Received figures)
kcal/kg: Net CV = Gross CV - 50.6H - 5.85M - 0.191O
MJ/kg: Net CV = Gross CV - 0.212H - 0.0245M - 0.0008O
Btu/lb: Net CV = Gross CV - 91.2H - 10.5M - 0.34O
– where M is % Moisture, H is % Hydrogen, O is % Oxygen (from ultimate
analysis*, also As Received).
*Ultimate analysis determines the amount of carbon, hydrogen, oxygen, nitrogen & sulphur.
For typical bituminous coal with 10% M and 25% Volatile Matter, the
differences between gross and net calorific values are approximately as follows:

260 kcal/kg                                           1.09 MJ/kg                                                    470 Btu/lb



FACT SHEET 03

 Power Generation
1 MWh = 3600 MJ
1 MW = 1 MJ/s
1 MW (thermal power) [MWth] = approx 1000 kg steam/hour
1 MW (electrical power) [MWe] = approx MW (thermal power)
3
A 600 MWe coal-fired power station operating at 38% efficiency and 75%
overall availability will consume approximately:
– Bituminous coal (CV 6000 kcal/kg NAR*): 1.5 Mt/year
– Brown coal    (CV 2250 kcal/kg NAR*): 4.0 Mt/year
Sources: GWC Coal Handbook & IEA Clean Coal Centre

From GAR to NAR
The difference between net and gross as received (NAR v/s GAR) specific energy values is the latent heat of the water vapor which lowers the effective calorific value in the boiler.
To convert from GAR to NAR for bituminous coals subtract approximately:
1.09 mj/kg 
                                                                          260 kcal/kg                                                          470 btu/lb
Applicable for bituminous coal. Not to be considered exact!

FC = Fixed Carbon % by weight on Moisture and Ash Free basis
VM = Volatile Matter % by Weight on Moisture and Ash Free Basis 


Hydrogen % ( Moisture and Ash free basis ) = VM * [ 7.35 / (VM + 10) - 0.013 ]
Nitrogen % ( Moisture and Ash free basis ) = 2.1 – 0.012 * VM)
Carbon % ( Moisture and Ash free basis) = { [FC + 0.9 * (VM-14)] – Sulphur %}
Sulphur % has to be assumed based on some previous analysis.

Convert all the above to Air Dried Basis or As Received Basis, as per the Ash % and Moisture % in the proximate sample. Then Subtract from 100 to get Oxygen %. 


From ADB to GAR
GCV (ARB) = GCV (ADB) X (100-TM)/(100-IM)

e.g.
ADB 6300 x (100-18)/(100-12) = 5870 GAR 
NAR (kcal/kg) = GAR (kcal/kg) – 50.7H – 5.83TM
NAR is NCV ARB.
GAR is GCV ARB.
H = Hydrogen is usually in DB or DAF and needs to be converted to ARB 
H is assumed as 5.4 DAF (regional variance used in lieu of Ultimate Analysis)
GCV (ADB) ke GCV (ARB) = 5,514 kcal/kg
H (DAF) ke H (ARB) = 4.18%
NCV (ARB) = 5,191 kcal/kg
Gross ADB (GAD) = 5,766 kcal/kg
Gross ARB (GAR) = 5,514 kcal/kg
Net ARB (NAR) = 5,191 kcal/kg